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Reaction of heteroorganic chalcogenides with some mercury derivatives

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Bis(triethylsilyl) selenide, bis(triethylsilyl) telluride, and their germanium analogs, react with mercury salts, HgX2 (X=Cl, CN), forming the mercury chalcogenide and the compound (C2H5)3MX (M=Si, Ge).

  2. 2.

    The reaction of [(C2H5)3Si]2Se with ethylmercury chloride gives triethylchlorosilane and bis(ethylmercury) selenide.

  3. 3.

    By reacting hydrochalcogenides of the series (C2H5)3SiXH (X=S, Se, Te) with bis(triethylgermyl)-mercury, using either a 1∶1 or a 1∶2 ratio, were respectively synthesized derivatives of the type (C2H5)3Si-XHgGe(C2H5)3 and [(C2H5)3SiX]2Hg.

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSR, USSR

    M. N. Bochkarev, L. P. Maiorova, A. I. Charov & N. S. Vyazankin

Authors
  1. M. N. Bochkarev
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  2. L. P. Maiorova
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  3. A. I. Charov
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  4. N. S. Vyazankin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1375–1379, June, 1972.

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Bochkarev, M.N., Maiorova, L.P., Charov, A.I. et al. Reaction of heteroorganic chalcogenides with some mercury derivatives. Russ Chem Bull 21, 1324–1327 (1972). https://doi.org/10.1007/BF00854554

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  • DOI: https://doi.org/10.1007/BF00854554

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