Conclusions
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1.
A study was made of the reaction of theπ-allyl compounds of palladium with the halides of divalent germanium and tin; SnCl2 inserts itself at the Pd-Cl bond with the formation of the complexπ-C3-H5PdSnCl3·P(C6H5)3.
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2.
Decomposition of theπ-allylpalladium halides occurs when reaction is with germanium halides, with the formation of biallyl; the triphenylphosphine complexes of palladium were isolated when triphenylphosphine was added to the reaction mixture.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1368–1372, June, 1972.
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Gubin, S.P., Rubezhov, A.Z., Voronchikhina, L.I. et al. Reaction of π-allyl compounds of pallidium with Ge(II) and Sn(II) halides. Russ Chem Bull 21, 1317–1320 (1972). https://doi.org/10.1007/BF00854552
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DOI: https://doi.org/10.1007/BF00854552