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Crystal chemical investigation of sulfidofluorides of the rare earth metals of the samarium group

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    SmSF, GdSF, DySF, HoSF, and ErSF were synthesized; their densities were measured.

  2. 2.

    SmSF, GdSF, DySF crystallized in the PbFCl structural type, while HoSF and ErSF do not belong to this type.

  3. 3.

    The parameters of the unit cell and the interatomic distances in SmSF, GdSF, and DySF were determined. The IR spectra of sulfidofluorides of the rare earth metals of the samarium group were taken and interpreted.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1254–1257, June 1972.

The authors would like to express their gratitude to S. S. Batsanov for his valuable advice and discussion of the results and to L. R. Batsanova for performing the chemical analyses.

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Filatkina, V.S., Kustova, G.N. Crystal chemical investigation of sulfidofluorides of the rare earth metals of the samarium group. Russ Chem Bull 21, 1213–1215 (1972). https://doi.org/10.1007/BF00854528

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  • DOI: https://doi.org/10.1007/BF00854528

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