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Catalysts produced by the reduction of salts of metals of group VIII with sodium borohydride

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The metal (M=Ni, Co) and the boride of the transition metal with composition M2B are present in the precipitates obtained in the reduction of nickel and cobalt salts with sodium borohydride, after their heating in an atmosphere of argon at 400°.

  2. 2.

    In the reduction of chlorplatinic acid and palladium chloride with sodium borohydride, the metals Pt andα-Pd are formed.

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Literature cited

  1. R. Paul, P. Buisson, and N. Joseph, Compt. Rend.,232, 627 (1951).

    Google Scholar 

  2. H. C. Brown and C. A. Brown, J. Amer. Chem. Soc.,84, 1492 (1962).

    Google Scholar 

  3. H. C. Brown and C. A. Brown, J. Amer. Chem. Soc.,84, 2827 (1962).

    Google Scholar 

  4. B. D. Polkovnikov, A. A. Balandin, and A. M. Taber, Dokl. Akad. Nauk SSSR,145, 809 (1962).

    Google Scholar 

  5. N. V. Tremasov, Dissertation [in Russian], Kazan' (1968).

  6. Yu. D. Kondrashov and V. F. Gladkova, Tr. In-ta Prikladnoi Khimii,46, 268 (1960).

    Google Scholar 

  7. A. Stock and E. Kuss, Ber.,47, 810 (1914).

    Google Scholar 

  8. H. I. Schlesinger, H. C. Brown, A. E. Finholt, J. R. Gilbreath, H. R. Hoekstra, and E. K. Hyde, J. Amer. Chem. Soc.,75, 215 (1953).

    Google Scholar 

  9. N. N. Mal'tseva, Z. K. Steplyadkina, and V. I. Mikheeva, Zh. Neorgan. Khim.,11, 720 (1966).

    Google Scholar 

  10. L. I. Mirkin, Manual of x-Ray Diffraction Analysis of Polycrystals [in Russian], Fizmatgiz (1961).

  11. K. I. Portnoi, V. M. Chubarov, V. M. Romashov, M. Kh. Levinskaya, and S. E. Salibekov, Dokl. Akad. Nauk SSSR,169, 1104 (1966).

    Google Scholar 

  12. R. M. Adams, Boron, Metalloboron Compounds and Boranes, Interscience Publ. (1964).

  13. R. Fruchart, Liebigs Ann. Chem.,4, 1201 (1959).

    Google Scholar 

  14. M. I. Blok, M. N. Kozlova, N. F. Lashko, and K. A. Shpunt, Dokl. Akad. Nauk SSSR,113, 811 (1957).

    Google Scholar 

  15. R. Blume, J. Phys. Radium,13, 430 (1952).

    Google Scholar 

  16. S. Rundgvist, Acta Chem. Scand.,13, 1193 (1959).

    Google Scholar 

  17. L. J. E. Hofer, J. F. Shultz, R. D. Panson, and R. B. Anderson, Inorgan. Chem.,3, 1783 (1964).

    Google Scholar 

  18. P. Thonnart, P. Lenfant, and L. Claude, Compt. Rend.,258, 5207 (1964).

    Google Scholar 

  19. P. Lenfant, C. Legras, and B. Kervella, Compt. Rend.,260, 1636 (1965).

    Google Scholar 

  20. F. A. Lewis, The Palladium Hydrogen System, Academic Press, London-New York (1967).

    Google Scholar 

  21. Z. Csuros and I. Petro, Acta Chim. Hung.,29, 351 (1961).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    Z. K. Sterlyadkina, N. N. Mal'tseva, G. D. Frangulyan, B. D. Polkovnikov & V. M. Bakulina

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, USSR

    Z. K. Sterlyadkina, N. N. Mal'tseva, G. D. Frangulyan, B. D. Polkovnikov & V. M. Bakulina

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  1. Z. K. Sterlyadkina
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  2. N. N. Mal'tseva
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  3. G. D. Frangulyan
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  4. B. D. Polkovnikov
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  5. V. M. Bakulina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1240–1245, June, 1972.

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Sterlyadkina, Z.K., Mal'tseva, N.N., Frangulyan, G.D. et al. Catalysts produced by the reduction of salts of metals of group VIII with sodium borohydride. Russ Chem Bull 21, 1200–1204 (1972). https://doi.org/10.1007/BF00854525

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  • DOI: https://doi.org/10.1007/BF00854525

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