The formation of barium ozonide and superoxide in the reaction of ozone with barium peroxide

  • I. I. Vol'nov
  • S. A. Tokareva
  • V. N. Belevskii
  • V. I. Klimanov
  • G. P. Pilipenko
Inorganic and Analytical Chemistry
  • 60 Downloads

Conclusions

  1. 1.

    The possibility of formation of barium ozonide Ba(O3)2 containing ∼82% of the basis substance by the reaction of ozone dissolved in freon-12 with a suspension of barium peroxide in the same medium at −100 to −105° was demonstrated.

     
  2. 2.

    Barium ozonide is thermally stable below −70°.

     
  3. 3.

    The primary decomposition product of barium ozonide is the superoxide Ba(O2)2.

     

Keywords

Peroxide Ozone Superoxide Barium Decomposition Product 

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Literature cited

  1. 1.
    I. A. Kazarnovskii, G. P. Nikol'skii, and T. A. Abletsova, Dokl. Akad. Nauk SSSR,64, 69 (1949).Google Scholar
  2. 2.
    I. I. Vol'nov, S. A. Tokareva, V. I. Klimanov, and G. P. Pilipenko, Izv. Akad. Nauk SSSR, Ser. Khim., 1267 (1966).Google Scholar
  3. 3.
    I. I. Vol'nov, M. S. Dobrolyubova, and A. B. Tsentsiper, Izv. Akad. Nauk SSSR, Ser. Khim., 1665 (1966).Google Scholar
  4. 4.
    I. I. Vol'nov and V. V. Matveev, Izv. Akad. Nauk SSSR, Otd. Khim., 1136 (1963).Google Scholar
  5. 5.
    I. I. Vol'nov, S. A. Tokareva, V. N. Belevskii, and G. P. Pilipenko, Izv. Akad. Nauk SSSR, Ser. Khim., 416 (1967).Google Scholar
  6. 6.
    S. Z. Makarov and N. K. Grigor'eva, Zh. Prikl. Khimii,32, 2184 (1959).Google Scholar
  7. 7.
    I. I. Vol'nov, S. A. Tokareva, V. N. Belevskii, and V. I. Klimanov, Izv. Akad. Nauk SSSR, Ser. Khim., 1411 (1967).Google Scholar
  8. 8.
    R. Prish, Complexones in Chemical Analysis [Russian translation], IL (1955), pp.282, 346.Google Scholar
  9. 9.
    E. Seyb and J. Kleinberg, Analyt. Chem.,23, No. 1, 115 (1951).Google Scholar
  10. 10.
    A. D. McLachlam and M. C. R. Symons, J. Chem. Soc., 953 (1959).Google Scholar
  11. 11.
    J. E. Bennet, J. E. Ingram, M. C. R. Symons, P. George, and J. S. Griffith, Philos. Mag.,46, 443 (1955); Proc. Phys. Soc.,A69, 556 (1956).Google Scholar
  12. 12.
    M. Malley, J. Molec. Spectrosc.,17, 210 (1965).Google Scholar
  13. 13.
    T. Henriksen, Radiation Res.,23, 63 (1964).PubMedGoogle Scholar
  14. 14.
    I. I. Vol'nov, S. A. Tokareva, V. N. Belevskii, and E. I. Latysheva, Izv. Akad. Nauk SSSR, Ser. Khim., 513 (1970).Google Scholar
  15. 15.
    J. P. Couglin, Bull. 542, Bureau of Mines, Washington (1954).Google Scholar
  16. 16.
    S. A. Shukarev, Inorganic Chemistry [in Russian], Vysshaya Shkola (1970), p. 171.Google Scholar
  17. 17.
    Selected Values of Chemical Thermodynamic Properties Circular 500, Bureau of Standards, Washington (1953).Google Scholar

Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • I. I. Vol'nov
    • 1
  • S. A. Tokareva
    • 1
  • V. N. Belevskii
    • 1
  • V. I. Klimanov
    • 1
  • G. P. Pilipenko
    • 1
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of Sciences of the USSRUSSR

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