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Structure of paramagnetic dimers in the system: Dimethyl-2,6-di-tert-butyl-2,5-cyclohexadienone-sodium

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The ESR spectra were employed in making a study of the structure of the paramagnetic dimers obtained from the anion-radical of 4,4-dimethyl-2,6-di-tert-butyl-2,5-cyclohexadienone and sodium cations.

  2. 2.

    Data were obtained to support a variable orientation of the fragments of the dimer with respect to the nuclei of the sodium cation.

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Literature cited

  1. A. I. Prokof'ev, S. P. Solodovnikov, A. A. Volod'kin, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 644 (1972).

  2. N. Hirota, J. Phys. Chem.,71, 127 (1967).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 933–934, April, 1972.

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Prokof'ev, A.I., Solodovnikov, S.P., Volod'kin, A.A. et al. Structure of paramagnetic dimers in the system: Dimethyl-2,6-di-tert-butyl-2,5-cyclohexadienone-sodium. Russ Chem Bull 21, 883–885 (1972). https://doi.org/10.1007/BF00854493

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  • DOI: https://doi.org/10.1007/BF00854493

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