Skip to main content
SpringerLink
Log in

Acid-base properties of hydroxodiamino complexes of tetravalent platinum

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Two previously undescribed compounds, EnBr2(OH)2Pt and EnI2(OH)2Pt, were produced and characterized.

  2. 2.

    The acid dissociation constants (pK) of aqua groups in the complexes EnBr2(H2O)2Pt2+, EnI2(H2O)2·Pt2+, and EnCl2ClH2OPt+ were determined by the method of potentiometric titration with calculation according to Bjerrum.

  3. 3.

    A dispersion analysis was made of the results obtained, revealing the influence of the temperature of the experiment and concentration of the complexes on the values of pK.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. M. M. Yakshin and L. I. Baranova, Zh. Neorgan. Khimii,9, 1979 (1959).

    Google Scholar 

  2. M. M. Yakshin and L. I. Baranova, Zh. Neorgan. Khimii,8, 1710 (1960).

    Google Scholar 

  3. I. I. Chernyaev, N. N. Zheligovskaya, Leti-K'en, and D. V. Kurganovich, Zh. Neorgan. Khimii,8, 562 (1964).

    Google Scholar 

  4. J. Bjerrum, The Formation of Metal Amines in Aqueous Solution [Russian translation], IL (1961).

  5. M. G. Felin, N. N. Zheligovskaya, and Vikt. I. Spitsyn, Dokl. Akad. Nauk SSSR,199, 156 (1971).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    M. G. Felin, D. A. Murashov, N. N. Zheligovskaya & Vikt I. Spitsyn

Authors
  1. M. G. Felin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. A. Murashov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. N. Zheligovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Vikt I. Spitsyn
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 790–792, April, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Felin, M.G., Murashov, D.A., Zheligovskaya, N.N. et al. Acid-base properties of hydroxodiamino complexes of tetravalent platinum. Russ Chem Bull 21, 749–750 (1972). https://doi.org/10.1007/BF00854465

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00854465

Keywords

Search

Navigation