Isomerization of 3β-acetyl-α-3,4-epoxycarane

  • B. A. Arbuzov
  • Z. G. Isaeva
  • N. D. Ibragimova
Brief Communications


3β-Acetyl-α-3,4-epoxycarane under the influence of bases is easily rearranged to theα,β-unsaturated ketol, namely 3β-acetyl-4-caren-3-ol, by the E2 mechanism of theβ-elimination reaction.


These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    B. A. Arbuzov, Z. G. Isaeva, and N. D. Ibragimova, Dokl. Akad. Nauk SSSR,195, 91 (1970).Google Scholar
  2. 2.
    Z. G. Isaeva, Dissertation [in Russian], Kazan (1967).Google Scholar
  3. 3.
    J. K. Crandall and Luan-Ho Chang, J. Org. Chem.,32, 435 (1967).Google Scholar
  4. 4.
    J. K. Crandall and Luan-Ho Chang, J. Org. Chem.,33, 2375 (1968).Google Scholar
  5. 5.
    W. Kirchof, Ber.,93, 2712 (1960).Google Scholar
  6. 6.
    L. I. Zakharkin and I. M. Khorlina, Izv. Akad. Nauk SSSR, Ser. Khim., 862 (1965).Google Scholar
  7. 7.
    L. H. Briggs, R. C. Cambie, and P. S. Rutledge, J. Chem. Soc., 5374 (1963).Google Scholar
  8. 8.
    Beilstein, Vol. VII, Berlin (1928), p. 262.Google Scholar
  9. 9.
    H. Gilman and R. G. Jones, in: Organic Reactions, Vol. 6, New York (1951), p. 339.Google Scholar
  10. 10.
    J. B. Lewis and G. W. Hedrick, J. Org. Chem.,30, 4271 (1965).Google Scholar

Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • B. A. Arbuzov
    • 1
  • Z. G. Isaeva
    • 1
  • N. D. Ibragimova
    • 1
  1. 1.A. M. Butlerov Chemical InstituteV. I. Ul'yanov-Lenin Kazan State UniversityUSSR

Personalised recommendations