Formation of nitrene complexes of rhenium by the reaction of oxo derivatives of rhenium with phenyl isocyanate

  • I. S. Kolomnikov
  • Yu. D. Koreshkov
  • T. S. Lobeeva
  • M. E. Vol'pin
Brief Communications

Conclusions

Phenyl isocyanate can be a source of nitrenes when it is oxidized by the oxo complexes of the transition metals. The nitrene fragment can be trapped by the complex of the transition metal.

Keywords

Nitrene Phenyl Isocyanate Rhenium Phenyl Isocyanate 

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Literature cited

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    J. A. Conner and E. O. Fischer, J. Chem. Soc., A, 578 (1969).Google Scholar
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    E. O. Fischer and A. Maasböl, Chem. Ber.,100, 2445 (1967).Google Scholar
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    J. Ashley-Smith, M. Green, N. Mayne, and F. G. A. Stone, Chem. Commun., 409 (1969).Google Scholar
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    J. Chatt and G. A. Rowe, J. Chem. Soc., 4028 (1962).Google Scholar

Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • I. S. Kolomnikov
    • 1
  • Yu. D. Koreshkov
    • 1
  • T. S. Lobeeva
    • 1
  • M. E. Vol'pin
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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