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Synthesis of nitroalkyl-N-nitrosamines

  • R. G. Gafurov
  • E. M. Sogomonyan
  • L. T. Eremenko
Brief Communications
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Conclusions

  1. 1.

    Nitroalkylamines of variable structure were nitrosated by nitrous acid and its chloro- and fluoro-derivatives. On the example of 1,1,1,6,6,6-hexanitro-3-azapentane it was shown that weakly basic amines do not react with ClNO in nonpolar organic solvents.

     
  2. 2.

    The obtained nitroalkyl-N-nitrosamines are smoothly converted to N-nitramines by treatment with cone, nitric acid, but are not oxidized by trifluoroperacetic acid.

     

Keywords

Nitric Acid Organic Solvent Variable Structure Chloro ClNO 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1972

Authors and Affiliations

  • R. G. Gafurov
    • 1
  • E. M. Sogomonyan
    • 1
  • L. T. Eremenko
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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