Potentiometric study of the state of π-allylpalladium chloride in neutral aqueous solutions

  • N. G. Satsko
  • A. P. Belov
  • I. I. Moiseev
  • Ya. K. Syrkin
Brief Communications
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Conclusions

  1. 1.

    Employing a silver chloride electrode, a potentiometric study was made of the stateπ-allylpalladium chloride in neutral aqueous solutions.

     
  2. 2.

    The following complexes exist in neutral aqueous solutions ofπ-allylpalladium chloride: (C3H5Pd·Cl)2, C3H5PdCl·H2O, C3H5Pd(H2O) 2 + . The values of the mutual transformation constants of these complexes were determined.

     

Keywords

Chloride Aqueous Solution Silver Chloride Silver Chloride Electrode Mutual Transformation 

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Literature cited

  1. 1.
    W. E. Oberhanshi and L. F. Dahl, J. Organometal. Chem.,3, 43 (1965).Google Scholar
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    B. F. G. Johnson, J. Lewis, and D. A. White, J. Am. Chem. Soc.,91, 5186 (1969).Google Scholar
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    L. A. Katsman, M. N. Vargaftik, A. P. Belov, and Ya. K. Syrkin, Izv. Akad. Nauk SSSR, Ser. Khim., 1091 (1971).Google Scholar
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    W. J. Hornibrook, G. J. Janz, and A. R. Gordon, J. Am. Chem. Soc.,64, 513 (1942).Google Scholar

Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1972

Authors and Affiliations

  • N. G. Satsko
    • 1
  • A. P. Belov
    • 1
  • I. I. Moiseev
    • 1
  • Ya. K. Syrkin
    • 1
  1. 1.M. V. Lomonosov Institute of Fine Chemical Technology. N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of Sciences of the USSRUSSR

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