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Conclusions

Silicoacetylenic ethers and bromoethers were synthesized by the reaction of silylethynylmagnesium bromides withα-halo ethers. The bromoethers when heated with amines eliminate hydrogen bromide and are converted to the corresponding silicon-containing alkoxyenynes.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2579–2580, November, 1971.

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Komarov, N.V., Yarosh, O.G. & Vakhrushev, L.P. Organosilicon acetylenic ethers. Russ Chem Bull 20, 2447–2449 (1971). https://doi.org/10.1007/BF00854334

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  • DOI: https://doi.org/10.1007/BF00854334

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