Conclusions
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1.
The intensities of a number of lines of the symmetric stretching and deformation vibrations of the C-NO2 group of some polynitro- andα-halopolynitroalkanes were measured.
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2.
Rules for the changes in the intensity as a function of the nature of the substituent were found.
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3.
An increase in the intensity is mainly due to a decrease in the electron-acceptor capacity of the substituent and in its degree of polarizability.
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Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2575–2577, November, 1971.
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Levin, A.A., Khutoretskii, V.M., Okhlobystina, L.V. et al. Raman spectra of polynitro- andα-halopolynitroalkanes. Russ Chem Bull 20, 2442–2443 (1971). https://doi.org/10.1007/BF00854332
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DOI: https://doi.org/10.1007/BF00854332