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Reaction of fluoroolefins with salts of thiol acids

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the reactions of perfluoroisobutylene, perfluoropropylene, and perfluorocyclobutene with the salts of thiol acids, and specifically with potassium O,O-diethyl dithiophosphate, potassium thiocyanate, sodium thiosulfate, and sodium hydrosulfide.

  2. 2.

    The reaction of perfluoroisobutylene with potassium O,O-diethyl dithiophosphate is a convenient method for the preparation of the dimer of bis(trifluoromethyl)thio ketene.

  3. 3.

    It was shown that the thiocyanate anion has an ambident nature in the reaction with perfluoroisobutylene.

  4. 4.

    The reaction of perfluoro-2-azapropene with potassium O,O-diethyl dithiophosphate is a convenient method for the preparation of trifluoromethyl isothiocyanate.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    S. R. Sterlin, L. G. Zhuravkova, B. L. Dyatkin & I. L. Knunyants

Authors
  1. S. R. Sterlin
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  2. L. G. Zhuravkova
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  3. B. L. Dyatkin
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  4. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2517–2522, November, 1971.

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Sterlin, S.R., Zhuravkova, L.G., Dyatkin, B.L. et al. Reaction of fluoroolefins with salts of thiol acids. Russ Chem Bull 20, 2386–2389 (1971). https://doi.org/10.1007/BF00854319

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  • DOI: https://doi.org/10.1007/BF00854319

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