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Synthesis and structure of some polychloroalkadienes

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The alkaline dehydrochlorination of some polychloroalkenes and 1, 1, 3, 3, 5-pentachloropentane in ethylcellosolve medium at 20–40° gave five previously unknown conjugated dienes that represent chlorinated homologs of chloroprene.

  2. 2.

    The stereochemistry of the dienes was studied employing IR and NMR spectroscopy, and also GLC. In the case of the cis-form the NMR signal from the H2 proton in the investigated dienes is shifted downfield by ~0.3 ppm when compared with the trans-form, which makes it possible to judge the ratio of the isomers in the obtained products.

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Literature cited

  1. E. Ts. Chukovskaya, N. A. Kuz'mina, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1198 (1969); 2343 (1970); Dokl. Akad. Nauk SSSR,188, 1073 (1969).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    T. T. Vasil'eva, P. V. Petrovskii, E. Ts. Chukovskaya & R. Kh. Freidlina

Authors
  1. T. T. Vasil'eva
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  2. P. V. Petrovskii
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  3. E. Ts. Chukovskaya
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  4. R. Kh. Freidlina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2512–2517, November, 1971.

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Vasil'eva, T.T., Petrovskii, P.V., Chukovskaya, E.T. et al. Synthesis and structure of some polychloroalkadienes. Russ Chem Bull 20, 2381–2385 (1971). https://doi.org/10.1007/BF00854318

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  • DOI: https://doi.org/10.1007/BF00854318

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