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Halogenation and thiylation reactions ofβ-silicoorganic vinyl ethers

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the chlorination and bromination of some trialkylsilylethyl vinyl ethers. The dichloro and dibromo derivatives that are obtained here are very unstable compounds.

  2. 2.

    β-Silicon-containing vinyl ethers are capable of reacting with thiols under both heterolytic and homolytic conditions.

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Literature cited

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  2. M. F. Shostakovskii, N. V. Komarov, I. I. Tsykhanskaya, and N. N. Vlasova, Izv. Akad. Nauk SSSR, Ser. Khim., 914 (1968).

  3. M. F. Shostakovskii, N. V. Komarov, and N. N. Vlasova, Zh. Obshch. Khim.,37, 1151 (1967).

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  4. M. F. Shostakovskii, Vinyl Ethers [in Russian], Izd. AN SSSR (1952).

  5. M. F. Shostakovskii, N. V. Komarov, N. N. Vlasova, and F. P. L'vova, Izv. Akad. Nauk SSSR, Ser. Khim., 2678 (1967).

  6. J. F. Arens, in: Progress in Organic Chemistry [Russian translation], Vol. 2, Mir (1964), p. 113.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    N. N. Vlasova, I. I. Tsykhanskaya & F. P. L'vova

Authors
  1. N. N. Vlasova
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  2. I. I. Tsykhanskaya
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  3. F. P. L'vova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2509–2512, November, 1971.

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Vlasova, N.N., Tsykhanskaya, I.I. & L'vova, F.P. Halogenation and thiylation reactions ofβ-silicoorganic vinyl ethers. Russ Chem Bull 20, 2378–2380 (1971). https://doi.org/10.1007/BF00854317

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  • DOI: https://doi.org/10.1007/BF00854317

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