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Catalytic phosphorylation of polyfluorinated alcohols Communication 1. Preparation of tripolyfluoroalkyl and aryl polyfluoroalkyl phosphates

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A new method was developed for the catalytic phosphorylation of polyfluorinated alcohols.

  2. 2.

    In order to explain the catalytic action of the salts of metals of Groups I–III of the periodic system and of ammonium salts a scheme was proposed, which postulates reaction between the catalyst and the oxygen of the phosphoryl group, in this way facilitating nucleophilic substitution at the phosphorus atom.

  3. 3.

    A number of polyfluorotrialkyl phosphates and aryl polyfluoroalkyl phosphates was synthesized.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    L. S. Zakharov, V. V. Pisarenko, N. N. Godovikov & M. I. Kabachnik

Authors
  1. L. S. Zakharov
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  2. V. V. Pisarenko
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  3. N. N. Godovikov
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  4. M. I. Kabachnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2503–2509, November, 1971.

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Zakharov, L.S., Pisarenko, V.V., Godovikov, N.N. et al. Catalytic phosphorylation of polyfluorinated alcohols Communication 1. Preparation of tripolyfluoroalkyl and aryl polyfluoroalkyl phosphates. Russ Chem Bull 20, 2373–2377 (1971). https://doi.org/10.1007/BF00854316

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  • DOI: https://doi.org/10.1007/BF00854316

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