Conclusions
-
1.
A method was developed for the synthesis of cyclopentadienyl(CPD)-triaroxytitanes by the reaction of CPD-triethoxytitane with aryl acetates.
-
2.
Various CPD-triaroxytitanes were obtained for the first time, and a study was made of their chemical properties and IR spectra. A number of fluorophenoxy derivatives of mono- and bis-CPD-titane, containing various cyclopentadienyl radicals, was obtained, as well as the trifluoroacetates of the mono-and bis-CPD derivatives of titanium.
-
3.
In the alcoholysis of the CPD-triaroxytitanes the lability of the CPD ring changes as a function of the character of the substituent that is found in the aroxy group.
Similar content being viewed by others
Literature cited
A. N. Nesmeyanov, O. V. Nogina, and V. A. Dubovitskii, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1481 (1962).
G. G. Dvoryantseva, Yu. N. Sheinker, A. N. Nesmeyanov, O. V. Nogina, N. A. Lazareva, and V. A. Dubovitskii, Dokl. Akad. Nauk SSSR,161, 603 (1965).
A. N. Nesmeyanov, É. I. Fedin, P. V. Petrovskii, V. A. Dubovitskii, O. V. Nogina, and N. A. Lazareva, Dokl. Akad. Nauk SSSR,163, 659 (1965).
A. N. Nesmeyanov, V. A. Dubovitskii, O. V. Nogina, and V. N. Bochkarev, Dokl. Akad. Nauk SSSR,165, 125 (1965).
A. N. Nesmeyanov, E. I. Fedin, O. V. Nogina, N. S. Kochetkova, V. A. Dubovitsky, and P. V. Petrovsky, Tetrahedron Suppl.,8, Part II, 389 (1966).
A. N. Nesmeyanov, O. V. Nogina, N. A. Lazareva, and V. A. Dubovitskii, Izv. Akad. Nauk SSSR, Ser. Khim., 808 (1967).
A. N. Nesmeyanov, O. V. Nogina, and V. A. Dubovitskii, Izv. Akad. Nauk SSSR, Ser. Khim., 527 (1968).
A. N. Nesmeyanov, O. V. Nogina, and A. M. Berlin, Dokl. Akad. Nauk SSSR,134, 607 (1960).
A. N. Nesmeyanov, O. V. Nogina, and A. M. Berlin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 804 (1961).
A. N. Nesmeyanov, O. V. Nogina, A. M. Berlin, A. S. Girshovich, and G. V. Shatalov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 2146 (1961).
A. N. Nesmeyanov and O. V. Nogina, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 831 (1963).
H. Meister, Angew. Chem.,69, 533 (1957).
A. N. Nesmeyanov, O. V. Nogina, B. V. Lokshin, and V. A. Dubovitskii, Dokl. Akad. Nauk SSSR,182, 844 (1968).
A. N. Nesmeyanov, O. V. Nogina, V. A. Dubovitskii, B. A. Kvasov, P. V. Petrovskii, and N. A. Lazareva, Izv. Akad. Nauk SSSR, Ser. Khim., No. 12 (1971).
G. V. Drozdov, A. L. Klebanskii, and V. A. Bartashov, Zh. Obshch. Khim.,32, 2390 (1962).
K. Andrä, J. Organometal. Chem.,11, 567 (1968).
K. C. Pande and R. C. Mehrotra, J. Prakt. Chem.,5, No. 1, 101 (1957).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2482–2488, November, 1971.
Rights and permissions
About this article
Cite this article
Nesmeyanov, A.N., Nogina, O.V., Lazareva, N.A. et al. Synthesis of aroxy derivatives of cyclopentadienyl- and bis(cyclopentadienyl)titanium and fluoroacylates of mono- and bis(cyclopentadienyl) titanium. Russ Chem Bull 20, 2354–2359 (1971). https://doi.org/10.1007/BF00854312
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00854312