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Oxidation of the complex (C5H5)2TiCl·AlC2H5Cl2 by stannic chloride

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The complex (C5H5)2TiCl·AlC2H5Cl2 is oxidized by SnCl4 with the formation of a complex of (C5H5)2·TiCl2 with AlCl3 and SnCl2 as the basic product of this reaction.

  2. 2.

    Parallel with the oxidation of (C5H5)2TiCl by stannic chloride there is a competitive interaction of SnCl4 with organoaluminum compounds. When the mole ratio Al/Ti is increased, this reaction leads to a decrease in the effectiveness of the action of SnCl4 in the oxidation of (C5H5)2TiCl.

  3. 3.

    During the interaction with SnCl4, the complex (C2H5)2TiCl·AlC2H5Cl2 is partially converted to the complex (C5H5)2TiCl·AlCl3.

  4. 4.

    The oxidation of the complex (C5H5)2TiCl·AlC2H5Cl2 by CCl4 was studied. SiCl4 does not oxidize (C5H5)2TiCl, which is explained by the high energy of the Si-Cl bond.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    P. E. Matkovskii, T. I. Larkina, T. S. Dzhaviev, L. N. Russiyan, G. A. Beikhol'd, Kh. -M. A. Brikenshtein & N. M. Chirkov

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  1. P. E. Matkovskii
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  2. T. I. Larkina
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  3. T. S. Dzhaviev
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  4. L. N. Russiyan
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  5. G. A. Beikhol'd
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  6. Kh. -M. A. Brikenshtein
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  7. N. M. Chirkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2407–2412, November, 1971.

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Matkovskii, P.E., Larkina, T.I., Dzhaviev, T.S. et al. Oxidation of the complex (C5H5)2TiCl·AlC2H5Cl2 by stannic chloride. Russ Chem Bull 20, 2287–2291 (1971). https://doi.org/10.1007/BF00854297

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  • DOI: https://doi.org/10.1007/BF00854297

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