Conclusions
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1.
In the reaction of phenol, acetic and benzoic acids with an equimolar amount of bis(triethylgermyl) cadmium, there is a selective heterolysis of the Ge-Cd-Ge group, and phenoxy- or acyloxy(triethylgermyl) cadmium compounds are formed, respectively.
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2.
The reaction of benzoyl peroxide with bis(triethylgermyl)- and bis(triphenylgermyl) cadmium leads to selective cleavage of the heteroelement-heteroelement bonds.
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Literature cited
N.S. Vyazankin, G.A. Razuvaev, and O.A. Kruglaya, Organometal. Chem. Rev.,3, 323 (1968).
N.S. Vyazankin, V.T. Bychkov, O.V. Linzina, and G.A. Razuvaev, Dokl. Akad. Nauk SSSR,180, 101 (1969).
G. E. Coates and A. Lauder, J. Chem. Soc.,A264 (1966).
N.S. Vyazankin, E.N. Gladyshev, E.A. Fedorova, and G. A. Razuvaev, Dokl. Akad. Nauk SSSR,186, 1082 (1969).
O.A. Kryglaya, B.I. Petrov, and N.S. Vyazankin, Zh. Obshch. Khim.,39, 2365 (1969).
A. G. Lee, J. Organometal. Chem.,16, 321 (1969).
H.H. Anderson, J. Amer. Chem. Soc.,79, 326 (1957).
N. S. Vyazankin, G. A. Razuvaev, and V. T. Bychkov, Izv. Akad. Nauk SSSR, Ser. Khim., 1665 (1965).
N.S. Vyazankin, G.A. Razuvaev, and E.N. Gladyshev, Dokl. Akad. Nauk SSSR,151, 1326 (1963).
M. Lesbre and J. Satge, Compt. Rend.,254, 4051 (1962).
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The student L. Aleksandrova took part in the work.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2403–2406, November, 1971.
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Bychkov, V.T., Linzina, O.V., Razuvaev, G.A. et al. Reactions of selective cleavage of Ge-Cd bonds of bis-(triethylgermyl) cadmium. Russ Chem Bull 20, 2283–2286 (1971). https://doi.org/10.1007/BF00854296
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DOI: https://doi.org/10.1007/BF00854296