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Acetylenic condensation in the pyridine and pyridine N-oxide series

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    By replacing the halogen in theγ- andβ-iodopyridine N-oxides by the 3-methyl-3-hydroxybutynyl group we synthesized the N-oxides of tertiary pyridinylacetylenic alcohols. The alcohols were converted to the corresponding ethynylpyridine N-oxides by cleavage by the reverse Favorskii reaction.

  2. 2.

    α-Iodopyridine was condensed with a number of terminal acetylenic compounds.

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Literature cited

  1. M. S. Shvartsberg, I. L. Kotlyarevskii, A. N. Kozhevnikova, and V. N. Andrievskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1144 (1970).

  2. M. S. Shvartsberg, A. N. Kozhevnikova, and I. L. Kotlyarevskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1833 (1971).

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Siberian Branch of the Academy of Sciences of the USSR, USSR

    A. N. Kozhevnikova, M. S. Shvartsberg & I. L. Kotlyarevskii

Authors
  1. A. N. Kozhevnikova
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  2. M. S. Shvartsberg
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  3. I. L. Kotlyarevskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1168–1170, May, 1973.

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Kozhevnikova, A.N., Shvartsberg, M.S. & Kotlyarevskii, I.L. Acetylenic condensation in the pyridine and pyridine N-oxide series. Russ Chem Bull 22, 1132–1134 (1973). https://doi.org/10.1007/BF00854273

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  • DOI: https://doi.org/10.1007/BF00854273

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