Skip to main content
SpringerLink
Log in

Kinetics of reaction of some anion-radicals with tertiary butyl chloride

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Conclusions

  1. 1.

    The nature of the metal and the solvent has an important effect on the kinetics of the reaction of the anion-radicals of benzophenone and perylene with tert-butyl chloride.

  2. 2.

    The changes in the reactivity of the anion-radicals is related to the character of the ion pairs formed by the anion with the cation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. A. I. Prokof'ev, S. P. Solodovnikov, A. A. Volod'kin, and V. V. Ershov, Dokl. Akad. Nauk SSSR204, 114 (1972).

    Google Scholar 

  2. E. Warhurst and R. Whittaker, Trans. Faraday Soc.,62, 707 (1966).

    Google Scholar 

  3. D. I. Morants and E. Warhurst, Trans. Faraday Soc.,51, 1375 (1955).

    Google Scholar 

  4. M. Shwartz, Anionic Polymerization [Russian translation] Mir (1971).

  5. N. Hirota, J. Chem. Phys.,71, 127 (1967).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    R. Nasirov & S. P. Solodovnikova

Authors
  1. R. Nasirov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. P. Solodovnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1166–1168, May, 1973.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nasirov, R., Solodovnikova, S.P. Kinetics of reaction of some anion-radicals with tertiary butyl chloride. Russ Chem Bull 22, 1130–1131 (1973). https://doi.org/10.1007/BF00854272

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00854272

Keywords

Search

Navigation