Skip to main content
SpringerLink
Log in

Study of processes for complexing of acetylenic sulfones with aluminum bromide

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Employing the methods of IR spectroscopy, cryoscopy, and dialectrometric and calorimetric titrations, a study was made of the processes for the complexing of acetylenic sulfones with AlBr3. It was established that the complexes RSO2C≡CH·AlBr3 and RSO2C≡CH·2AlBr3 are formed in steps, with a coordination of the aluminum bromide via the oxygen atoms. The formation of the 1∶2 complex is accompanied by side processes.

  2. 2.

    We determined the values of the dipole moments and the −ΔH of the formed complexes, three of which (1∶2 composition) were isolated on a preparative scale.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. V. I. Laba, M. K. Polievktov, E. N. Prilezhaeva, and S. G. Mairanovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2149 (1969).

  2. E. N. Gur'yanova and I. P. Gol'dshtein, Zh. Organ. Khim., 2149 (1969).

  3. I. P. Gol'dshtein, E. N. Gur'yanova, and I. R. Karpovich, Zh. Fiz. Khim.,39, 932 (1965).

    Google Scholar 

  4. V. A. Plotnikov, I. A. Sheka, and Z. Ya. Yankelevich, Zh. Organ. Khim.,9 868 (1939).

    Google Scholar 

  5. W. Fischer and O. Ralfs, Z. Anorg. Allgem. Chem.,205, 1 (1932).

    Google Scholar 

  6. V. V. Puchkova, E. N. Gur'yanova, R. R. Shifrina, and K. A. Kocheshkov, Dokl. Akad. Nauk SSSR,207, 886 (1972).

    Google Scholar 

  7. V. V. Puchkova, E. N. Gur'yanova, V. I. Laba, and E. N. Prilezhaeva, Izv. Akad. Nauk SSSR, Ser. Khim., 462 (1973).

  8. I. Lindqvist, Inorganic Adduct Molecules of Oxo Compounds, Springer-Verlag (1963), p. 74.

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. V. Puchkova, E. N. Gur'yanova, V. I. Laba & E. N. Prilezhaeva

Authors
  1. V. V. Puchkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. N. Gur'yanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. I. Laba
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. N. Prilezhaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1156–1158, May, 1973.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Puchkova, V.V., Gur'yanova, E.N., Laba, V.I. et al. Study of processes for complexing of acetylenic sulfones with aluminum bromide. Russ Chem Bull 22, 1117–1119 (1973). https://doi.org/10.1007/BF00854266

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00854266

Keywords

Search

Navigation