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Radical reaction of trinitromethane derivatives with cyclic ethers

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The photolysis of solutions of C(NO2)4, IC(NO2)3 and CH(NO2)3 in tetrahydrofuran and tetrahydropyran at 20° leads to the formation of the correspondingα-trinitromethyl derivatives of cyclic ethers. Data were obtained in support of a radical nonchain reaction mechanism.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    I. A. Leenson, G. B. Sergeev, O. P. Shitov, S. L. Ioffe & V. A. Tartakovskii

  2. M. V. Lomonosov Moscow State University, USSR

    I. A. Leenson, G. B. Sergeev, O. P. Shitov, S. L. Ioffe & V. A. Tartakovskii

Authors
  1. I. A. Leenson
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  2. G. B. Sergeev
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  3. O. P. Shitov
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  4. S. L. Ioffe
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  5. V. A. Tartakovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1149–1151, May, 1973.

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Leenson, I.A., Sergeev, G.B., Shitov, O.P. et al. Radical reaction of trinitromethane derivatives with cyclic ethers. Russ Chem Bull 22, 1108–1110 (1973). https://doi.org/10.1007/BF00854263

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  • DOI: https://doi.org/10.1007/BF00854263

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