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Vibrational spectra of π-allyliron tricarbonyl derivatives in the region of the frequencies of the CO stretching vibrations

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The IR spectra of 15 derivatives ofπ-allyliron tricarbonyl in the region of the stretching vibrations of the CO groups were obtained.

  2. 2.

    The X substituents affect the cis-CO group predominantly by an inductive mechanism, while the mesomeric effect plays an important role in the transfer of the effect to the trans-CO group.

  3. 3.

    Substituents in the allyl ligand also affect the multiple nature of the CO bonds, although to a less degree than do substituents that are attached directly to the iron atom.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    T. B. Chenskaya, B. V. Lokshin & I. I. Kritskaya

Authors
  1. T. B. Chenskaya
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  2. B. V. Lokshin
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  3. I. I. Kritskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1146–1148, May, 1973.

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Chenskaya, T.B., Lokshin, B.V. & Kritskaya, I.I. Vibrational spectra of π-allyliron tricarbonyl derivatives in the region of the frequencies of the CO stretching vibrations. Russ Chem Bull 22, 1105–1107 (1973). https://doi.org/10.1007/BF00854262

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  • DOI: https://doi.org/10.1007/BF00854262

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