Conclusions
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1.
The thiooxin and diethanolamine complexes of vanadyl were obtained (in solution).
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2.
The EPR and optical spectroscopy methods were used to study the electronic structure of vanadyl compounds that contain sulfur, sulfur-nitrogen and nitrogen ligands.
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3.
It was shown that both the in-plane and the out-of-planeπ-bonds in the indicated compounds have to be taken into account.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1140–1142, May, 1973.
The authors express their gratitude to B. M. Kozyrev for his interest in the work, and to V. A. Shchukin for running the optical measurements.
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Zentsov, V.P., Luchkina, S.A. Study of electronic structure of some vanadyl compounds. Russ Chem Bull 22, 1097–1099 (1973). https://doi.org/10.1007/BF00854259
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DOI: https://doi.org/10.1007/BF00854259