Conclusions
The salt of a new completely aromatic ammonium cation, namely 4, 4-diphenyl-7-oxodibenzo-1, 4-dihydrodiazepinium iodide, was obtained, the structure of which was confirmed by qualitative tests with silver hydroxide, aqueous NaOH solution, and nitrosylsulfuric acid.
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Literature cited
A. N. Nesmeyanov, T. P. Tolstaya, A. V. Grib, and S. R. Kirgizbaeva, Dokl. Akad. Nauk SSSR,174, 856 (1967).
A. N. Nesmeyanov, T. P. Tolstaya, and A. V. Grib, Dokl. Akad. Nauk SSSR,153, 608 (1963).
A. N. Nesmeyanov, T. P. Tolstaya, A. V. Grib, N. F. Sokolova, and L. E. Orlova, Dokl. Akad. Nauk SSSR,199, 610 (1971).
D. Hellwinkel and H. Seifert, Chem. Commun., 1683 (1968).
A. N. Nesmeyanov, T. P. Tolstaya, and L. S. Isaeva, Dokl. Akad. Nauk SSSR,104, 872 (1955).
A. N. Nesmeyanov and T. P. Tolstaya, Dokl. Akad. Nauk SSSR,105, 95 (1955).
R. B. Sandin, J. Amer. Chem. Soc.,74, 274 (1952).
L. Mascarelli, Atti R. Acad. Lincei,16, 562 (1907); Chem. Zentr., 79 I, 134 (1908).
A. N. Nesmeyanov, T. P. Tolstaya, I. N. Lisichkina, S. E. Fokina, and S. V. Tsoi, Dokl. Akad. Nauk SSSR,178, 860 (1968).
H. Mehner, J. Prakt. Chem.,63, 266 (1901).
V. V. Lapshin, Dissertation [in Russian], MGU (1970), p. 48.
P. A. Smith, J. Amer. Chem. Soc.,75, 6335 (1953).
J. Piccard and M. Larsen, J. Amer. Chem. Soc.,39, 2006 (1917).
Organic Syntheses [Russian translation], Coll. Vol. 1, p. 420 (1950).
J. Thiele, Ann. Chem.,305, 102 (1899); J. Houben-Weyl, Methoden der Organischen Chemie,4, Auflage, Band 11/1, p. 428.
J. Piccard and R. Q. Brewster, J. Amer. Chem. Soc.,43, 2630 (1921).
H. Meyer, Monatsh. Chem.,22, 426 (1901).
G. Schroeter and O. Eisleb, Ann. Chem.,367, 128 (1909); E. Erdmann, Ber.,36, 3480 (1903).
K. Weigand and G. Hilgetag, Experimental Methods in Organic Chemistry [Russian translation], Khimiya (1968), p. 434.
C. C. Finger, J. Amer. Chem. Soc.,69, 1944 (1972).
Organic Syntheses [Russian translation], Coll. Vol. 3 (1958), p. 338.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1096–1101, May, 1973.
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Nesmeyanov, A.N., Tolstaya, T.P., Grib, A.V. et al. Synthesis of 4,4-diphenyl-7-oxodibenzodihydro-1,4-diazepinium salts. Russ Chem Bull 22, 1052–1056 (1973). https://doi.org/10.1007/BF00854248
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DOI: https://doi.org/10.1007/BF00854248