Investigation of the kinetics of the isomerization of n-pentane on the hydrogen form of mordenite at low partial pressures of hydrogen

  • V. V. Kharlamov
  • V. I. Garanin
  • Kh. M. Minachev
Physical Chemistry
  • 70 Downloads

Conclusions

  1. 1.

    The kinetics of the isomerization of n-pentane on the H-form of mordenite was investigated at partial pressures of hydrogen of 2–6 atm.

     
  2. 2.

    The degree of deactivation of the catalyst and the corrected reaction rate under these conditions were determined.

     
  3. 3.

    The heat and entropy of the formation of the n-amyl cation were determined, and an independent approximate calculation of these parameters was performed.

     

Keywords

Hydrogen Entropy Partial Pressure Mordenite Approximate Calculation 

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Literature cited

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    Kh. M. Minachev, V. I. Garanin, and V. V. Kharlamov, Izv. Akad. Nauk SSSR, Ser. Khim., 835 (1970).Google Scholar
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    Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, T. A. Isakova, and É. É. Senderov, Izv. Akad. Nauk SSSR, Ser. Khim., 1737 (1969).Google Scholar
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    V. I. Vedeneev, L. V. Gurvich, V. N. Kondrat'ev, V. A. Medvedev, and E. L. Frankevich, Cleavage Energies of Chemical Bonds. Ionization Potentials and Electron Affinity, Handbook [in Russian], Izd-vo AN SSSR (1962).Google Scholar
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    Ya. I. Gerasimov, V. P. Dreving, E. N. Eremin, A. V. Kiselev, V. P. Lebedev, G. M. Panchenkov, and A. I. Shlygin, Course in Physical Chemistry [in Russian], Vol. 1, Khimiya (1969).Google Scholar

Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • V. V. Kharlamov
    • 1
  • V. I. Garanin
    • 1
  • Kh. M. Minachev
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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