Conclusions
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1.
The kinetics of the isomerization of n-pentane on the H-form of mordenite was investigated at partial pressures of hydrogen of 2–6 atm.
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2.
The degree of deactivation of the catalyst and the corrected reaction rate under these conditions were determined.
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3.
The heat and entropy of the formation of the n-amyl cation were determined, and an independent approximate calculation of these parameters was performed.
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Kh. M. Minachev, V. I. Garanin, and V. V. Kharlamov, Izv. Akad. Nauk SSSR, Ser. Khim., 835 (1970).
Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, T. A. Isakova, and É. É. Senderov, Izv. Akad. Nauk SSSR, Ser. Khim., 1737 (1969).
V. I. Vedeneev, L. V. Gurvich, V. N. Kondrat'ev, V. A. Medvedev, and E. L. Frankevich, Cleavage Energies of Chemical Bonds. Ionization Potentials and Electron Affinity, Handbook [in Russian], Izd-vo AN SSSR (1962).
Ya. I. Gerasimov, V. P. Dreving, E. N. Eremin, A. V. Kiselev, V. P. Lebedev, G. M. Panchenkov, and A. I. Shlygin, Course in Physical Chemistry [in Russian], Vol. 1, Khimiya (1969).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1006–1012, May, 1973.
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Kharlamov, V.V., Garanin, V.I. & Minachev, K.M. Investigation of the kinetics of the isomerization of n-pentane on the hydrogen form of mordenite at low partial pressures of hydrogen. Russ Chem Bull 22, 970–974 (1973). https://doi.org/10.1007/BF00854233
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DOI: https://doi.org/10.1007/BF00854233