Conclusions
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1.
A complete analysis of the proton AA′BB′ spectrum of 1,1,1,3-tetrachloropropane was carried out by the methods of homo-(INDOR) and heteronuclear1H{D} double resonance, with an electronic-computer calculation of the spectra according to an iteration program for the two working frequencies 60 and 90 MHz.
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2.
Using the NMR-1H spectrum of the deutero-analog 1,1,1,3-tetrachloro-3-d1-propane, the values of the geminal constants in the ClCH2(−10.7 Hz) and CCl3CH2 groups (−14.4 Hz) were determined.
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Literature cited
K. Mislow and M. Raban, Selected Problems of Stereochemistry [Russian translation], Mir (1970), p. 9.
N. Sheppard and J. J. Turner, Proc. Roy. Soc., A252, 506 (1955); H. S. Gutowsky, G. G. Belford, and R. E. McMahon, J. Chem. Phys.,36, 3353 (1962).
R. J. Abraham and K. G. R. Machler, Mol. Phys.,7, 165 (1964).
R. J. Abraham, L. Cavalli, and K. G. R. Pachler, Mol. Phys.,11, 471 (1966); R. J. Abraham and G. Gatti, J. Chem. Soc., B, 961 (1969).
D. Amesly, D. Finey, and L. Sutclif, High-Resolution NMR Spectroscopy [Russian translation], Chapter 8, 9, Mir (1968).
V. Spirko, Coll. Czechoslov. Chem. Comm.,35, 980 (1970).
A. U. Stepanyants, V. F. Vytrov, and A. V. Kagramanyan, Zh. Strukt. Khimii,12, 224 (1971).
C. W. Haigh and M. Kinns, Chem. Commun., 1502 (1969).
B. Dischler and W. Maier, Z. Naturforsch.,16, 318 (1961); B. Dischler and G. Englert, ibid.,16, 1180 (1961).
D. M. Grant, R. C. Hirst, and H. S. Gutowsky, J. Chem. Phys.,38, 470 (1963).
R. C. Hirst and D. M. Grant, J. Chem. Phys.,40, 1909 (1964).
T. K. Lim, A. Taurins, and M. A. Whitehead, Canad. J. Chem.,44, 1211 (1966).
B. A. Englin, T. A. Onishchenko, V. A. Valovoi, T. A. Babushkina, G. K. Semin, L. G. Zelenskaya, and R. Kh. Freidlina, Izv. Akad. NaukS SSR, Ser. Khim., 332 (1969).
L. C. Leitch and A. T. Morse, Canad. J. Chem.,30, 924 (1952); J. E. Frencis and L. C. Leitch, ibid.,35, 500 (1957).
T. Joshino and J. Komiyama, J. Polymer SCi.,B3, 311 (1965).
W. S. Brey, K. N. Scott, and D. R. Whitman, J. Phys. Chem.,72, 4351 (1968).
R. R. Ernst, J. Chem. Phys.,45, 3845 (1966).
É. T. Lippmaa, Zh. Strukt. Khimii,8, 717 (1967).
V. F. Bystrov and A. U. Stepanyan, in: Radiospectroscopic and Quantum Chemical Methods in Structural Investigations [in Russian], Nauka, (1967), pp. 147, 161; W. V. Philipsborn, Angew. Chemie, Internat. Edit.,10, 472 (1971).
A. B. Dempster, K. Price, and N. Sheppard, Spectrochim. Acta,A27, 1563 (1971).
V. F. Bystrov, Uspekhi Khimii,41, 512 (1972); S. Sternhell, Quart. Revs., London, Chem. Soc.,23, 236 (1969).
O. S. Tee and J. Warkentin, Canad. J. Chem.,43, 2424 (1965).
G. M. Whitesides, J. P. Sevenair, and R. W. Goetz, J. Amer. Chem. Soc.,89, 1135 (1967).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 982–989, May, 1973.
The authors would like to express their gratitude to T. T. Vasil'eva and A. A. Kamyshova for providing the 1,3,3,5-tetrachloropentane and 1,3,3-trichlorobutane.
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Énglin, B.A., Onishchenko, T.A., Belov, Y.V. et al. Complete analysis of the AA′BB′ NMR-1H spectrum of 1,1,1,3-tetrachloropropane by methods of hetero- and homonuclear double resonance. Russ Chem Bull 22, 947–953 (1973). https://doi.org/10.1007/BF00854229
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DOI: https://doi.org/10.1007/BF00854229