Conclusions
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1.
The values of the frequencies of the valence vibrations of the NO groups were found for a number of nitrosyl paramagnetic complexes of iron and chromium.
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2.
The NO group is coordinated with the central metal atom in the form of a cation.
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3.
A distinct correspondence was established between the parameters of the ESR and IR spectra and the peculiarities of the electronic structure of the complexes studied.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 975–979, May, 1973.
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Khalepp, B.P., Luchkina, S.A. & Ovchinnikov, I.V. Valence vibrations of the NO groups and ESR spectra of nitrosyl complexes of iron and chromium. Russ Chem Bull 22, 940–943 (1973). https://doi.org/10.1007/BF00854227
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DOI: https://doi.org/10.1007/BF00854227