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Study of the mechanism for the formation ofα-dinitromethyltetrahydrofuran in the reaction of tetranitromethane and its derivatives with tetrahydrofuran employing radiocarbon

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    α-Dinitromethyltetrahydrofuran is formed mainly fromα-trinitromethyltetrahydrofuran when tetranitromethane and its derivatives are reacted with THF.

  2. 2.

    The ratio of theα-trinitromethyl- andα-dinitromethyltetrahydrofurans when XC(NO2)3(X=H, NO2) is reacted with THF depends on the stoichiometry of the starting reactants and the nature of the solvent. The amount ofα-dinitromethyltetrahydrofuran increases when excess THF is used.

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Literature cited

  1. O. P. Shitov, S. L. Ioffe, V. A. Tartakovskii, and S. S. Novikov, Izv. Akad. Nauk SSSR, Ser. Khim., 490 (1972).

  2. G. V. Isagulyants and A. A. Balandin, Kinetika i Kataliz,5, 737 (1961).

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  3. Yu. I. Derbentsev and G. V. Isagulyants, Usp. Khim.,38, 1597 (1969).

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  4. O. P. Shitov, S. L. Ioffe, V. A. Tartakovskii, S. S. Novikov, N. N. Rozhdestvenskaya, and G. V. Isagulyants, this issue, p. 117.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    O. P. Shitov, S. L. Ioffe, T. N. Golovina, V. A. Tartakovskii, S. S. Novikov, N. N. Rozhdestvenskaya & G. V. Isagulyants

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  1. O. P. Shitov
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  2. S. L. Ioffe
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  3. T. N. Golovina
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  4. V. A. Tartakovskii
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  5. S. S. Novikov
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  6. N. N. Rozhdestvenskaya
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  7. G. V. Isagulyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 124–126, January, 1973.

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Shitov, O.P., Ioffe, S.L., Golovina, T.N. et al. Study of the mechanism for the formation ofα-dinitromethyltetrahydrofuran in the reaction of tetranitromethane and its derivatives with tetrahydrofuran employing radiocarbon. Russ Chem Bull 22, 119–121 (1973). https://doi.org/10.1007/BF00854132

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  • DOI: https://doi.org/10.1007/BF00854132

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