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Reaction ofα-dinitromethyl derivatives of cyclic ethers with trinitromethane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Under the influence of trinitromethane, theα-dinitromethyl derivatives of cyclic ethers are converted to the corresponding trinitromethyl derivatives.

  2. 2.

    Employing the method of labeled atoms, it was shown that in this reaction the C(NO2)2H group in the starting compound is replaced completely by the trinitromethane C(NO2)3 group.

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Literature cited

  1. O. P. Shitov, S. L. Ioffe, V. A. Tartakovskii, and S. S Novikov, Izv. Akad. Nauk SSSR, Ser. Khim., 490 (1972).

  2. S. S. Novikov, K. K. Babievskii, and V. A. Shlyapochnikov, Dokl. Akad. Nauk SSSR,141, 875 (1971).

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  3. J. Meisenheimer and M. Schwarz, Ber.,39, 2551 (1906).

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  4. Organic Syntheses [Russian translation], Vol. 3, IL (1952), p. 411.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    O. P. Shitov, S. L. Ioffe, V. A. Tartakovskii, S. S. Novikov, N. N. Rozhdestvenskaya & G. V. Isagulyants

Authors
  1. O. P. Shitov
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  2. S. L. Ioffe
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  3. V. A. Tartakovskii
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  4. S. S. Novikov
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  5. N. N. Rozhdestvenskaya
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  6. G. V. Isagulyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 122–124, January, 1973.

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Shitov, O.P., Ioffe, S.L., Tartakovskii, V.A. et al. Reaction ofα-dinitromethyl derivatives of cyclic ethers with trinitromethane. Russ Chem Bull 22, 117–118 (1973). https://doi.org/10.1007/BF00854131

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  • DOI: https://doi.org/10.1007/BF00854131

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