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14-hydroxysteroids

Communication 6. Configuration of 3-methyl ether of (±)-14β-hydroxy-9(11)-dehydro-8α-d-homoestrone

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Employing a number of chemical transformations, as well as the IR and NMR spectra, we corroborated the anti-cis-configuration for the 3-methyl ether of 14β-hydroxy-9(11)-dehydro-8α-D-homoestrone, which was proposed previously on the basis of the mass-spectrometric fission data.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 96–100, January, 1973.

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Zakharychev, A.V., Kasymov, S.K., Ananchenko, S.N. et al. 14-hydroxysteroids. Russ Chem Bull 22, 88–91 (1973). https://doi.org/10.1007/BF00854121

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  • DOI: https://doi.org/10.1007/BF00854121

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