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Esters of trivalent phosphorus thioacids

Communication 13. Reaction of acid chlorides of trivalent phosphorus acids with allyl mercaptan and allyl alcohol

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dihalophosphines, S-alkyl dichlorothiophosphites, and S,S-dialkyl chlorodithiophosphites react with allyl mercaptan to give derivatives of allylalkyl(aryl)thiophosphinic acids and allylthiophosphonic acids.

  2. 2.

    The reaction proceeds via the corresponding trivalent phosphorus derivatives, which are isomerized to the pentavalent phosphorus compounds.

  3. 3.

    The reaction of S-alkyl dichlorothiophosphites, S,S-dialkyl chlorodithiophosphites, and the acid chloride-esters of thiophosphonous acids with allyl alcohol leads to the formation of the derivatives of trivalent phosphorus thioacids.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    N. I. Rizpolozhenskii, V. D. Akamsin & R. M. Eliseenkova

Authors
  1. N. I. Rizpolozhenskii
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  2. V. D. Akamsin
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  3. R. M. Eliseenkova
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Additional information

See [1] for preliminary communication.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 85–89, January, 1973.

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Rizpolozhenskii, N.I., Akamsin, V.D. & Eliseenkova, R.M. Esters of trivalent phosphorus thioacids. Russ Chem Bull 22, 77–81 (1973). https://doi.org/10.1007/BF00854119

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  • DOI: https://doi.org/10.1007/BF00854119

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