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Esters of trivalent phosphorus thioacids

Communication 12. Esters of ethyl(phenyl)-β-cyanoalkylthiol-phosphinic and ethyl(phenyl)-γ-ketoalkylthiolphosphinic acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of the acid chloride-esters of thiophosphonous acids with the nitriles ofα,β-un-saturated acids in the presence of either CH3COOH or water leads to the formation of the esters of alkyl-(aryl)-β-cyanoalkylthiolphosphinic acids, while the esters ofβ-cyanoalkyldithiophosphinic acids are formed in the presence of CH3COSH.

  2. 2.

    The reaction of the acid chloride-esters of ethyl(phenyl)thiophosphonous acids withα,β-unsaturated ketones in the presence of either CH3COOH or water leads to the formation of the esters of ethyl(phenyl)-γ-ketoalkylthiolphosphinic acids.

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Literature cited

  1. V. D. Akamsin and N. I. Rizpolozhenskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1976 (1967).

  2. N. I. Rizpolozhenskii, V. D. Akamsin, R. M. Eliseenkova, and R. R. Shagidullin, Izv. Akad. Nauk SSSR, Ser. Khim., 2765 (1972).

  3. L. J. Bellamy, New Data on the Infrared Spectra of Complex Molecules [Russian translation], Mir (1971), p. 220.

  4. L. J. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL (1963), pp. 189, 378.

  5. C. N. R. Rao, Chemical Applications of Infrared Spectroscopy, New York (1963), p. 296.

  6. V. Mark, C. H. Dungen, M. M. Crutchfield, and J. R. Wazer, Topics in Phosphorus Chemistry,5, 227 (1968).

    Google Scholar 

  7. A. N. Pudovik, V. K. Khairullin, and G. V. Dmitrieva, Dokl. Akad. Nauk SSSR,174, 372 (1967).

    Google Scholar 

  8. V. K. Khairullin, G. V. Dmitrieva, and A. N. Pudovik, Izv. Akad. Nauk SSSR, Ser. Khim., 871 (1970).

  9. A. N. Pudovik, M. A. Vasyanina, and V. K. Khairullin, Zh. Obshch. Khim.,40, 1030 (1970).

    Google Scholar 

  10. V. K. Khairullin, R. M. Kondrat'eva, and A. N. Pudovik, Izv. Akad. Nauk SSSR, Ser. Khim., 2097 (1967).

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    V. D. Akamasin, R. M. Eliseenkova & N. I. Rizpolozhenskii

Authors
  1. V. D. Akamasin
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  2. R. M. Eliseenkova
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  3. N. I. Rizpolozhenskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 80–84, January, 1973.

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Akamasin, V.D., Eliseenkova, R.M. & Rizpolozhenskii, N.I. Esters of trivalent phosphorus thioacids. Russ Chem Bull 22, 72–76 (1973). https://doi.org/10.1007/BF00854118

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  • DOI: https://doi.org/10.1007/BF00854118

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