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1-aryl-3-tert-butyl-3-hydroxytrlazenes

Communication 1. Synthesis and oxidative decomposition

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We synthesized a number of p-substituted 1-aryl-3-tert-butyl-3-hydroxytriazenes. Their oxidation with lead peroxide leads to cleavage, with the formation of aryl radicals, nitrogen and 2-nitroso-2-methylpropane.

  2. 2.

    The EPR spectrum of p-nitrophenyl-tert-butyl nitroxide was obtained, which differs from that described previously in the literature. An interpretation of the spectrum is given.

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Literature cited

  1. G. A. Abakumov, V K. Cherkasov, and G. A. Razuvaev, Dokl. Akad. Nauk SSSR,197, 823 (1971).

    Google Scholar 

  2. G A. Razuvaev, G. A. Abakumov, and V. K. Cherkasov, Dokl. Akad. Nauk SSSR,198, 601 (1971).

    Google Scholar 

  3. G. A. Razuvaev, L. G. Abakumova, G. A. Domrachev, and G. A. Abakumov, Dokl. Akad. Nauk SSSR,197, 1315 (1971).

    Google Scholar 

  4. K. Torssell, Tetrahedron,26, 2759 (1970).

    Google Scholar 

  5. H. Lemaire, Y. Marechal, R. Ramasseul, and A. Rassat, Bull. Soc. Chim. France, 372 (1965).

  6. Organic Syntheses [Russian translation], Vol. 4, IL (1953), p. 107.

  7. N. Kornblum, R. Gluter, and W. Jones, J. Amer. Chem. Soc.,78, 4003 (1956).

    Google Scholar 

  8. E. Bamberger and E. Renauld, Ber.,30, 2278 (1897).

    Google Scholar 

  9. K. Weigand and G. Hilgetag, Experimental Methods in Organic Chemistry [Russian translation], Khimiya (1968), p. 539.

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Translated from Izvestiya Akademiya Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 68–71, January, 1973.

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Razuvaev, G.A., Abakumov, G.A., Sanaeva, É.P. et al. 1-aryl-3-tert-butyl-3-hydroxytrlazenes. Russ Chem Bull 22, 61–63 (1973). https://doi.org/10.1007/BF00854115

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  • DOI: https://doi.org/10.1007/BF00854115

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