Conclusions
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1.
Depending on the conditions, the following reactions take place when the phenyl derivatives of the Mo and W cyclopentadienyl carbonyls are reacted with P(C6H5)3 and P(OC6H5)3: replacement of CO, insertion of CO, and replacement of the cyclopentadienyl and phenyl rings.
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2.
Only exchange by phosphorus ligands was observed for the phosphorus-containing complexes.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 62–67, January, 1973.
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Nesmeyanov, A.N., Ustynyuk, N.A., Bogatyreva, L.V. et al. Reaction of phenyl derivatives of metal carbonyls of molybdenum and tungsten with triphenylphosphine and triphenyl phosphite. Russ Chem Bull 22, 55–60 (1973). https://doi.org/10.1007/BF00854114
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DOI: https://doi.org/10.1007/BF00854114