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Cyclic unsaturated compounds

Communication 45. 1,4-Elimination of elements of water in substituted cyclopentenols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Together with the classical 1,2-elimination of the elements of water, 1,4-elimination takes place in the dehydration of the substituted 2-cyclopenten-1-ols, accompanied by migration of the double bond.

  2. 2.

    The data obtained make it possible to predict the cases where the synthesis of the substituted cyclopentadienes is accompanied by the formation of noticeable amounts of 3-methylene-1-cyclopentenes (dienes with a fixed transoid system of double bonds).

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Authors and Affiliations

  1. N. D. Zelinskii for Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. A. Mironov & A. A. Akhrem

Authors
  1. V. A. Mironov
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  2. A. A. Akhrem
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Additional information

See [1] for Communication 44 in this series.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 38–45, January, 1973.

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Mironov, V.A., Akhrem, A.A. Cyclic unsaturated compounds. Russ Chem Bull 22, 34–39 (1973). https://doi.org/10.1007/BF00854109

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  • DOI: https://doi.org/10.1007/BF00854109

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