Conclusions
The photodecomposition of ferric chloride in a polycarbonate based on 1,1-di-(4-hydroxyphenyl)-1-phenylethane leads to cleavage of the macromolecule at the carbonate group and the formation of radicals presumably of the phenyl type, which are localized on the macrochains.
Literature cited
E. Ya. Davydov, O. A. Ledneva, Yu. A. Mikheev, G. B. Pariiskii, and D. Ya. Toptygin, Dokl. Akad. Nauk SSSR,195, 875 (1970).
D. Ya. Toptygin, G. B. Pariiskii, E. Ya. Davydov, O. A. Ledneva, and Yu. A. Mikheev, Vysokomolekul. Soedin.,A14, 1534 (1972).
G. B. Pariiskii, D. Ya. Toptygin, E. Ya. Davydov, O. A., Ledneva, Yu. A. Mikheev, and V. M. Karasev, Vysokomolekul. Soedin.,B14, 511 (1972).
D. Campbell, K. Araki, and D. T. Turner, J. Polymer Sci.,A1, 2597 (1966).
N. M. Bazhin, Kinetika i Kataliz,8, 532 (1967).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 642–644, March, 1973.
Rights and permissions
About this article
Cite this article
Ledneva, O.A., Davydov, E.Y., Pariiskii, G.B. et al. Transformation of polycarbonate based on 1,1-di-(4-hydroxyphenyl)-1-phenylethane under the influence of light in the presence of ferric chloride. Russ Chem Bull 22, 614–615 (1973). https://doi.org/10.1007/BF00854037
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00854037