Kinetic study of reaction of tri-tert-butylphenoxyl radical with hydrogen halides
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The EPR method was used to study the reaction of the 2,4,6-tri-tert-butylphenoxyl radical with HCl and HBr.
The approximate values of the energies of the C-X bonds in the molecules of the 4-bromo- and 4-chloro-2,4,6-tri-tert-butylcyclohexadien-2,5-ones were calculated.
KeywordsHydrogen Kinetic Study Halide Hydrogen Halide
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- 1.A. I. Prokof'ev, S. P. Solodovnikov, A. A. Volod'kin, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 182 (1971).Google Scholar
- 2.A. M. Vasserman, A. L. Buchachenko, G. A. Nikiforov, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 1947 (1967).Google Scholar
- 3.V. I. Vedneev, L. V. Gurvich, and V. N. Kondrat'ev, Energy of Rupture of Chemical Bonds. Ionization Potentials and Electron Affinity [in Russian], Izd. AN SSSR (1962).Google Scholar