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dπ − pπ Interaction in bonds of silicon with halogens

  • A. N. Egorochkin
  • N. S. Vyazankin
  • S. Ya. Khorshev
  • T. I. Chernysheva
  • O. V. Kuz'min
Brief Communications

Conclusions

  1. 1.

    In monohalosilanes the ability of the halogens for dσ − pπ interaction decreases in the series F >Cl >Br >I.

     
  2. 2.

    In silanes with several halogen atoms, dσ − pπ interaction is determined by the value of the charge on the silicon atom, which depends both on the inductive effect of the halogen atoms and on the dσ − pπ bonds already present in the molecule.

     

Keywords

Silicon Silane Halogen Silicon Atom Inductive Effect 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • A. N. Egorochkin
    • 1
  • N. S. Vyazankin
    • 1
  • S. Ya. Khorshev
    • 1
  • T. I. Chernysheva
    • 1
  • O. V. Kuz'min
    • 1
  1. 1.Institute of ChemistryAcademy of Sciences of the USSRUSSR

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