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Interaction of benzoyl and trichloroacetyl isocyanates with electrophilic reagents

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Benzoyl and trichloroacetyl isocyanates react with electrophilic reagents with greater difficulty than with nucleophilic reagents.

  2. 2.

    Benzoyl isocyanate reacts with ethylpropionate, propargylmethyl ether, and cis-dichloroethylene according to a scheme of 1,2-cycloaddition.

  3. 3.

    Trichloroacetyl isocyanate interacts with propargylmethyl ether according to the type of 1,2-cy-cloaddition and according to the type of substitutional addition.

  4. 4.

    A dimer of benzoyl isocyanate was produced, and its structure was established.

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Literature cited

  1. B. A. Arbuzov and N. N. Zobova, Dokl. Akad. Nauk SSSR,170, 1317 (1966).

    Google Scholar 

  2. B. A. Arbuzov, N. N. Zobova, and É. G. Yakova, Izv. Akad. Nauk SSSR, Ser. Khim., 1114 (1969).

  3. R. E. Shozda, Organ. Chem.,32, 2960 (1967).

    Google Scholar 

  4. A. Baeyer, Chem.,18, 2269 (1885).

    Google Scholar 

  5. W. Reppe and Mitarbeitern, Liebigs Ann. Chem.,596, 74 (1955).

    Google Scholar 

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Author information

Authors and Affiliations

  1. V. I. Ul'yanov-Lenin Kazan' State University, USSR

    B. A. Arbuzov, N. N. Zobova & F. B. Balabanova

Authors
  1. B. A. Arbuzov
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  2. N. N. Zobova
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  3. F. B. Balabanova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1570–1574, July, 1970.

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Arbuzov, B.A., Zobova, N.N. & Balabanova, F.B. Interaction of benzoyl and trichloroacetyl isocyanates with electrophilic reagents. Russ Chem Bull 19, 1479–1482 (1970). https://doi.org/10.1007/BF00853839

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  • DOI: https://doi.org/10.1007/BF00853839

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