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Force constants of CH bonds in small rings

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    For three-membered rings the values of the force constants of the CH bonds [Kq (CH)x] substantially exceed the corresponding values in four-, five- and six-membered rings.

  2. 2.

    The Kq (CH) values in three-membered rings are close to the Kq (CH) values of olefinic compounds.

  3. 3.

    The nature of the heteroatom of the ring has comparatively little effect on the value of Kq (CH).

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Literature cited

  1. L. M. Sverdlov and E. P. Krainov, Opt. i Spektroskopiya,3, 54 (1957).

    Google Scholar 

  2. J. L. Duncan and G. R. Burns, J. Mol. Spectr.,30, 253 (1969).

    Google Scholar 

  3. L. A. Gribov, Introduction to the Theory and Calculation of the Vibrational Spectra of Multiatomic Molecules [in Russian], Izd. LGU (1965).

  4. J. Johansen, Z. Physik. Chem.,227, 305 (1964).

    Google Scholar 

  5. V. T. Aleksanyan, Dissertation [in Russian], Moscow (1970).

  6. J. W. Russell, M. Bishop, and J. Limburg, Spectrochim. Acta.25A, 1929 (1969).

    Google Scholar 

  7. R. W. Mitchell, L. J. Kirma, R. J. Pirkle, and J. A. Merritt, Spectrochim. Acta,25A, 819 (1969).

    Google Scholar 

  8. V. T. Aleksanyan and G. M. Kuz'yants, Zh. Strukt. Khim.,12, 266 (1971).

    Google Scholar 

  9. R. W. Mitchell, F. A. Hartmann, and J. A. Merritt, J. Mol. Spectr.,31, 388 (1969).

    Google Scholar 

  10. R. Ettinger, J. Chem. Phys.,40, 1693 (1964).

    Google Scholar 

  11. R. C. Lord and S. Nakagawa, J. Chem. Phys.,39, 2951 (1963).

    Google Scholar 

  12. L. M. Sverdlov and N. I. Prokof'eva, Opt. i Spektroskopiya,7, 588 (1959).

    Google Scholar 

  13. G. N. Zhizhin, Dissertation [in Russian], Moscow (1965).

  14. M. V. Vol'kenshtein, M. A. El'yashevich, and B. I. Stepanov, Vibrations of Molecules [in Russian], GONTI (1949), Vol. 1.

  15. J. H. Schachtschneider and R. G. Snyder, Spectrochim. Acta,19, 117 (1963).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    E. R. Razumova & V. T. Aleksanyan

Authors
  1. E. R. Razumova
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  2. V. T. Aleksanyan
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1191–1193, May, 1972.

The authors express their deep gratitude to D. S. Bystrov (Scientific-Research Physical Institute of the Leningrad University) for supplying the programs and for consultation on operating with them.

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Razumova, E.R., Aleksanyan, V.T. Force constants of CH bonds in small rings. Russ Chem Bull 21, 1145–1146 (1972). https://doi.org/10.1007/BF00853792

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  • DOI: https://doi.org/10.1007/BF00853792

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