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Stereochemistry of wittig reaction of mercurated ylids with aldehydes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Only the trans-trans olefin, containing mercury, is formed when benzaldehyde is reacted with mercuri-bis-triphenylphosphinocarbomethoxymethylene.

  2. 2.

    The reaction of acetaldehyde with the same ylid leads to a mixture of the cis-cis and trans-trans olefins.

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Literature cited

  1. N. A. Nesmeyanov, A. V. Kalinin, and O. A. Reutov, Zh. Organ. Khim.,5, 1508 (1969).

    Google Scholar 

  2. N. A. Nesmeyanov, A. V. Kalinin, and O. A. Reutov, Dokl. Akad. Nauk SSSR,195, 98 (1970).

    Google Scholar 

  3. C. Ruchardt, P. Panse, and S. Eichler, Chem. Ber.,100, 1144 (1967).

    Google Scholar 

  4. D. W. Moore and J. A. Happe, J. Phys. Chem.,65, 224 (1961).

    Google Scholar 

  5. D. Moy, M. T. Emerson, and J. P. Oliver, Inorg. Chem.,2, 1261 (1963).

    Google Scholar 

  6. S. Cawley and S. S. Danyluk, J. Phys. Chem.,68, 1240 (1964).

    Google Scholar 

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, Moscow

    Nik A. Nesmeyanov, A. V. Kalinin, V. S. Petrosyan & O. A. Reutov

Authors
  1. Nik A. Nesmeyanov
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  2. A. V. Kalinin
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  3. V. S. Petrosyan
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  4. O. A. Reutov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1189–1191, May, 1972.

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Nesmeyanov, N.A., Kalinin, A.V., Petrosyan, V.S. et al. Stereochemistry of wittig reaction of mercurated ylids with aldehydes. Russ Chem Bull 21, 1142–1144 (1972). https://doi.org/10.1007/BF00853791

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  • DOI: https://doi.org/10.1007/BF00853791

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