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Polymerization of 1,8-nonadiyne on the catalytic system Al(C2H5)3-TiCl4

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the polymerization of 1,8-nonadiyne on the catalytic system A1(C2H5)3-TiCl4.

  2. 2.

    The polymeric derivatives of a trisubstituted benzene that are formed during the polycyclotrimerization of 1,8-nonadiyne lead to the formation of soluble polycyclophanes as the result of subsequent intramolecular cyclotrimerization of the triple bonds, and to the formation of insoluble products by intermolecular crosslinking.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    A. A. Berlin, V. D. Ermakova & M. I. Cherkashin

Authors
  1. A. A. Berlin
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  2. V. D. Ermakova
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  3. M. I. Cherkashin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1185–1186, May, 1972.

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Berlin, A.A., Ermakova, V.D. & Cherkashin, M.I. Polymerization of 1,8-nonadiyne on the catalytic system Al(C2H5)3-TiCl4 . Russ Chem Bull 21, 1136–1138 (1972). https://doi.org/10.1007/BF00853789

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  • DOI: https://doi.org/10.1007/BF00853789

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