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Effect of unsymmetrical substitution on the nuclear quadrupole resonance spectra of trivalent antimony

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Very strong asymmetrization of the electron distribution on the central atom occurs for the unsymmetrically substituted compounds of trivalent antimony, which is expressed in a noticeable increase of the asymmetry parameter and the constants of the quadrupole bond for121Sb and123Sb when compared with compounds of the SbX3 type.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    G. K. Semin, E. V. Bryukhova, T. A. Babushkina, V. I. Svergun, A. E. Borisov & N. V. Novikova

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  1. G. K. Semin
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  2. E. V. Bryukhova
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  3. T. A. Babushkina
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  4. V. I. Svergun
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  5. A. E. Borisov
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  6. N. V. Novikova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1183–1184, May, 1972.

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Semin, G.K., Bryukhova, E.V., Babushkina, T.A. et al. Effect of unsymmetrical substitution on the nuclear quadrupole resonance spectra of trivalent antimony. Russ Chem Bull 21, 1134–1135 (1972). https://doi.org/10.1007/BF00853788

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  • DOI: https://doi.org/10.1007/BF00853788

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