Conclusions
-
1.
In all cases dimethyldichlorosilane reacts with a replacement of the chlorine atom by the phenyl groups of diphenyldichlorosilane and triphenylchlorosilane.
-
2.
Dimethylphenylchlorosilane and diphenylmethylchlorosilane react only with an exchange of the organic radical, in which connection with a predominant exchange of the methyl group in the case of dimethylphenylchlorosilane, and of the phenyl group in the case of diphenylmethylchlorosilane. The temperature, reaction time and ratio of the starting reactants all influence the composition of the reaction products.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
V. N. Penskii, V. V. Ponomarev, S. A. Golubtsov, and K. A. Andrianov, Izv. Akad. Nauk SSSR, Ser. Khim., 876 (1972).
V. N. Penskii, V. V. Ponomarev, S. A. Golubtsov, and K. A. Andrianov, Izv. Akad. Nauk SSSR, Ser. Khim., 880 (1972).
V. N. Penskii, V. V. Ponomarev, S. A. Golubtsov, and K. A. Andrianov, Izv. Akad. Nauk SSSR, Ser. Khim., 1898 (1971).
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1145–1149, May, 1972.
Rights and permissions
About this article
Cite this article
Penskii, V.N., Ponomarev, V.V., Golubtsov, S.A. et al. Catalytic reaction of phenylchlorosilanes with methylchlorosilanes. Russ Chem Bull 21, 1096–1099 (1972). https://doi.org/10.1007/BF00853776
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00853776