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Anodic fluorination of benzene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the possibility of fluorination at high values of the anode potential.

  2. 2.

    Benzene under these conditions is fluorinated to fluorobenzene and difluorobenzene. Fluorobenzene forms difluorobenzene, and further fluorination fails to occur.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    I. N. Rozhkov, A. V. Bukhtiarov & I. L. Knunyants

Authors
  1. I. N. Rozhkov
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  2. A. V. Bukhtiarov
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  3. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1130–1133, May, 1972.

The authors express their deep gratitude to E. M. Mysov for the mass-spectrometric analysis of the products, and to V. I. Dostovalova for studying the products by the19F NMR method.

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Rozhkov, I.N., Bukhtiarov, A.V. & Knunyants, I.L. Anodic fluorination of benzene. Russ Chem Bull 21, 1082–1084 (1972). https://doi.org/10.1007/BF00853773

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  • DOI: https://doi.org/10.1007/BF00853773

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