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Stereochemistry and reactivity of unsaturated compounds

Communication 15. Synthesis and epimerization of 1-halomethyl-4, 6-dimethyl-3-cyclohexenes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The pure trans-isomers of the 1-bromomethyl-, 1-iodomethyl- and 1-chloromethyl-4, 6-dimethyl-3-cyclohexenes were synthesized.

  2. 2.

    A study was made of the epimerization of the 1-halomethyl- and 1-hydroxymethyl-4, 6-dimethyl-3-cyclohexenes under the influence of temperature and acid catalysts.

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Authors and Affiliations

  1. M. M. Shemyakin Institute of the Chemistry of Natural Compounds, Academy of Sciences of the USSR, USSR

    G. P. Kugatova-Shemyakina, V. M. Andreev & L. I. Rozhkova

Authors
  1. G. P. Kugatova-Shemyakina
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  2. V. M. Andreev
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  3. L. I. Rozhkova
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1102–1107, May, 1972.

The NMR spectra were taken by V. I. Sheichenko and were interpreted by T. M. Ivanova, to whom we express our sincere gratitude.

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Kugatova-Shemyakina, G.P., Andreev, V.M. & Rozhkova, L.I. Stereochemistry and reactivity of unsaturated compounds. Russ Chem Bull 21, 1056–1060 (1972). https://doi.org/10.1007/BF00853768

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  • DOI: https://doi.org/10.1007/BF00853768

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