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The catalytic hydrogenation of (+)-carvone on palladium and platinum catalysts

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The sequence of hydrogenation of carvone on platinum and palladium catalysts was investigated.

  2. 2.

    The hydrogenation of carvone on Pd-black proceeds nonselectively with the formation of carvotanacetone and carvomenthone. As a result of parallel reactions of isomerization and irreversible catalysis, carvacrol is formed. Palladium on carbon catalyzes the process differently from Pd-black.

  3. 3.

    Hydrogenation of carvone on Pt-black proceeds selectively through the successive formation of carvotanacetone, isomeric carvomenthones, and isomeric carvomenthols.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    E. I. Klabunovskii, L. F. Godunova & L. K. Maslova

Authors
  1. E. I. Klabunovskii
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  2. L. F. Godunova
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  3. L. K. Maslova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1063–1068, May, 1972.

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Klabunovskii, E.I., Godunova, L.F. & Maslova, L.K. The catalytic hydrogenation of (+)-carvone on palladium and platinum catalysts. Russ Chem Bull 21, 1020–1024 (1972). https://doi.org/10.1007/BF00853760

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  • DOI: https://doi.org/10.1007/BF00853760

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